Synthesis of Chitosan-Poly Aniline Conducting Nano Composite and its Structural Physical Properties

Document Type : Original Article

Author

MSc, Department of Food Science and Technology, Faculty of Agriculture, Institute of higher education Afagh, Orumieh, Iran

Abstract

The aim of this study was to investigate the effect of polyaniline conductive nano-polymer on the structural, functional and biological properties of chitosan bio-composite. In this study, conductive polyaniline nanoparticles were used to improve the structural properties of chitosan. For this purpose, chitosan-polyaniline nanocomposite in combination of different concentrations of polyaniline and synthesis time (1-60 minutes) with the aim of producing antibacterial and biodegradable packaging was synthesized; also physical, structural, and functional properties of the films were investigated. Structural properties were investigated using infrared spectroscopy and X-ray diffraction and also the size, shape and morphology of the synthesized particles were studied using scanning electron microscopy (SEM). The results showed that the polyaniline nanoparticles synthesized in the chitosan polymer matrix are spherical in dimensions of 45-50 nm. The study of the effect of polyaniline on the physical properties of chitosan films also showed that with increasing the concentration of polyaniline and the synthesis time, the water solubility and water vapor permeability of the films decreased. Also, due to the fading of synthesized nanocomposites at high concentrations of poly-aniline, synthesized nanocomposites can be used in the packaging of light-sensitive foods.

Keywords

References

1. Ghanbarzadeh, B., Almasi, H. (2011). "Physical properties of edible emulsified films based on carboxymethyl cellulose and oleic acid." International Journal of Biological Macromolecules, 48,44-49.##
2. Teng, B , k. G. (2012). “Strengthening of steel structures with fiber-reinforced polymer composites.” Journal of Constructional Steel Research, 78, 131-143.##
3. Alexsandre, M., and Dubois, P . (2000). "Polymer-layered silicate nanocomposites: preparation. Properties and uses of a new class of materials." Materials Science and Engineering: R :Reports 28, 1-63.##
4. Luo, Y ., and Wang. Q . (2013). "Recent advances of chitosan and its derivatives for novel applications in food science." J. Fd. Proc. Bev. 1.13.##
5. Je J. and Kim S., (2006) "Chitosan derivatives killed bacteria by disrupting the outer and inner membrane," Journal of Agricultural Food Chemistry, vol. 54, pp. 6629–6633.##
6. Rabea E.I., Badawy M.E.-T., Stevens C.V., Smagghe G., and W. S., (2003). "Chitosan as antimicrobial agent: Applications and mode of action," Biomacromolecules, vol. 4, pp. 1475–1465.##
Malinauskas A., (2001). "Chemical Decomposition of Conducting Polymers," Polymer, 42, 3957-3972. 7.##
8.Wesling B. and Postorefer J. (1999). "Corrosion Prevention with an Organic Metalo Po Trachora," M., Zemerk, J., Charls un. (2002). Czech Republic, 8, 180.lyaniline, Electrochimi Acta, 4, 2139-2147.##
9. Trachora, M., Zemerk, J., Charls un.(2002). Czech Ripublic, 8, 180.##
10. Pasquini, D., Teixeira, E. M., Curvelo, A.S., Belgasem, M. N., & Dufresne, A. (2008). "Surface esterification of cellulose Fibres: Processing and Characterisation of low – density polyethylene / cellulose fibres composites." Composites Science & Technology. 68:193-201.##
11. Peng, Y., Wu, Y., and Li, Y. (2013). "Development of tea extracts and chitosan composite film for active packaging materials." International journal of biological macromolecules 59, 282- 289.##
12. Mogadas Kia, E., Alizadeh, M., Wrdast, M., Rezazad, M. (2016). "Synthesis of nanoplimate of absorbent surface molecular mold Cholesterol based on magnetic iron-silica particles and functional properties review," Urmia Medical Journal Twenty-seventh volume, 3, 231-239.##
13. Han, j. H. (2014). "Chapter 9 - Edible Films and Coatings: A Review. In "Innovations in Food Packaging (Second Edition)" (J. H. Han, ed.), pp. 213-255. Academic Press, San Diego.##
14. Casariego, A., Souza, B., Cerqueira.m M., Texeira, J., Cruz, Diaz, R., and Vicente, A. (2009). "Chitosan0clay films properties as affected by biopolymer and clay micro/nanoparticales concentration." Food Hydrocolloids 23, 1895- 1902.##
15. Abdollahi, M., Alboofetileh, M., Behrooz, R., Rezaei, M., Miraki, R. (2013). “Reducing water sensitivity of alginate bio-nanocomposite film using cellulose nanoparticles.” International journal of biological macromolecules, 54, 166-173.##
16. Saadatmand, M., Yazdanshenas, M., Rezaie Zarachi, S., Yousefi Tellouri, B. (2012). "Antimicrobial activity of chitosan-TiO2 nanocomposite and its application on hospital sterilized gas. Journal of Experimental Sciences." Spring and Summer, 6, 1: 59-62.##
17. Z. Abdeen, Somaia G. Mohammad. (2014). "Study of the Adsorption Efficiency of an Eco-Friendly Carbohydrate Polymer for Contaminated Aqueous Solution by Organophosphorus Pesticide," Journal of Organic Polymer Materials, 4, 16-28.##
18. Pouget, J. P., Jozefowicz, M. E., Epstein, A. E. A., Tang, X., & MacDiarmid, A. G. (1991). “X-ray structure of polyaniline.” Macromolecules, 24(3), 779-789.‏##
19. Zilberman, M., Titelman, G. I., Siegmann, A., Haba, Y., Narkis, M., & Alperstein, D. (1997). “Conductive blends of thermally dodecylbenzene sulfonic acid‐doped polyaniline with thermoplastic polymers.” Journal of applied polymer science, 66(2), 243-253.##
20. Abdollahi, M.,Rezaei, M., and farzi, G. (2012). "A novel active bionanocomposite incorporating rosemary essential oil and nonoclay into chitosan." Journal of Food Engineering 111, 343- 350.Z. Abdeen, Somaia G.##
21. Z.-H. Zhang, Z. Han, X.-A. Zeng, X.-Y. Xiong, Y.-J. Liu. (2015). "Enhancing mechanical properties of chitosan films viamodification with vanillin," International Journal of Biological Macromolecules.##
22. Zhang, M., Li, X, H., Gong, Y, D., Zhao, N, M., Zhang, X, F. (2002). "Properties and biocompositebility of chitosan films modified by blending With PEG." Bio-mater., 23, 2641-2648.##
23. M. Trchov´a and J. Stejskal, Pure Appl.(2011). “Chemical Engineering Chem”., 83, 1803. 24##
24. A. G. Yavuz, A. Uygun and V. R.(2009). Bhethanabotla, Carbohydr. Polym., 75, 448.##
25. A. G. Yavuz, A. Uygun and V. R.(2010). "Bhethanabotla, Carbohydr." Polym., 81, 712.##
26. Khan, R., & Dhayal, M. (2009). “Chitosan/polyaniline hybrid conducting biopolymer base impedimetric immunosensor to detect”. Ochratoxin-A. Biosensors and Bioelectronics, 24(6), 1700-1705.##
27. A. G. Yavuz, A. Uygun and V. R.(2010). "Bhethanabotla," Carbohydr. Polym., 81, 712.##
28. Eslahi, N., Dadashian, F., Hematinejad, N. (2013 ). "Provides biodegradable packaging film using chitosan and gelatin." Quarterly Journal of the Promotion of Science and Technology, Year 4, issue 16, pp. 58-65.##
29. Ojag, M., Shariatmadari, F., Adeli, A., Kordjezi, M., Abdollahi M.( 2017). "Preparation of chitosan-kitty composite film and evaluation of its physical and mechanical properties." Quarterly Journal of Nutrition Sciences, Year 4, No. 15, pp. 151-161.##
30. Mirhosseini M., Yazdani Keshkooli, N. Dehghan, Ali. (2016). "Antimicrobial activity of chitosan-zinc oxide nanocomposite," Journal of Razi Journal of Nursing Sciences Volume 23, Issue 147.##
31. Bourtom , T.,and Chinnnan, M. S. (2008). "Preparation and properties of rice atarch-chitosan blend biodegradable film." LWT-Food Science and Technology 41 ,1633-1641.##
32. Casariego, A., Souza, B., Cerqueira.m M., Texeira, J., Cruz, Diaz, R., and Vicente, A. (2009). "Chitosan0clay films properties as affected by biopolymer and clay micro/nanoparticales concentration." Food Hydrocolloids 23, 1895- 1902.##
33. Zhong, Y., song, X. Y., Li, Y, F. (2011). "Antimicrobial, physical and mechanical properties of kudzu starch-chitosan composite film as a function of acid solvent types." Carbohydrate polymers, 84(1), 335-342.##
34. Rhim, J.W. (2011). "Effect of clay contents on mechanical and water vapor barrier propertie of agar-based nanocomposite films Carbohydrate Polymers," 86, 691- 699.##
35. Ojag, M., Shariatmadari, F., Adeli, A., Kordjezi, M., Abdollahi M. (2017). "Preparation of chitosan-kitty composite film and evaluation of its physical and mechanical properties." Quarterly Journal of Nutrition Sciences, Year 4, No. 15, pp. 151-161.##
36. Casariego, A., Souza, B., Cerqueira.m M., Texeira, J., Cruz, Diaz, R., and Vicente, A. (2009). "Chitosan0clay films properties as affected by biopolymer and clay micro/nanoparticales concentration." Food Hydrocolloids 23, 1895- 1902.##
37. Bourtom , T.,and Chinnnan, M. S.(2008). "Preparation and properties of rice atarch-chitosan blend biodegradable film." LWT-Food Science and Technology 41 ,1633-1641.##
38. Ojagh, S.M., Rezaei, M., Razavi, S.H,, and Hosseini, S.M.H. (2010). "Development and evaluation of a novel biodegradable film made from chitosan and cinnamon essential oil with low affinity toward water." Food Chemistry, 122, 161–166.##
Packaging Science and Art
Volume 11, Issue 42 - Serial Number 42
September 2020
Pages 80-92

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History

  • Receive Date: 20 April 2020
  • Revise Date: 20 May 2020
  • Accept Date: 22 August 2020
  • Publish Date: 20 September 2020

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